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1. |
The number of moles of solute present in 1000 ml of the water and aqueous solution are respectively called |
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a. Morarity & Morality |
b. Morality & Molarity |
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d. Normality & Molality |
: B |
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2. |
Boltzmann constant with respect to gas constant is |
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a. Gas constant for 100 molecules |
b. Gas constant for 10 mole of gas |
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d. Gas constant for 1 molecule only |
: D |
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3. |
When Fe(OH)3 sol is added to As2S3
sol, then |
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a. a new solution is formed |
b. an emulsion is formed |
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d. flocculation takes place |
: D |
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4. |
The number of significant digits in 0.00002 and 20,000 respectively are |
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a. 1 and 5 |
b. 1 and 1 |
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d. 6 and 5 |
: A |
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5. |
In fluorite structure, the arrangement of spheres is |
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a. acc |
b. hcc |
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d. ccp |
: D |
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6. |
1 mole of hydrated CuSO4 contains |
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a. 90 moles of water |
b. 90 atoms of water |
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d. 9 g of oxygen |
: C |
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7. |
During the extraction of Fe, slag obtained is |
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a. FeO |
b. FeSiO3 |
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d. CaSiO3 |
: D |
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8. |
Acetaminophen is a |
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a. analgesics |
b. disinfectant |
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d. none of these |
: C |
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9. |
Joule - Thomson effect is zero in the case of |
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a. Real gas |
b. Permanent gas |
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d. Non ideal gas |
: C |
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10. |
The enthalpies of elements in their standard states are taken as zero. Hence the enthalpy of formation of a compound |
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a. should always be negative |
b. should always be positive |
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d. may be positive or negative |
: D |
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11. |
To a mixture of acetic acid and sodium acetate a further amount of sodium acetate is added. The pH of the mixture: |
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a. increases |
b. decreases |
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d. not predictable |
: A |
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12. |
The product of atomic weight and specific heat for solid elements in k cal / mol is |
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a. 6.4 |
b. 5 |
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d. 5.6 |
: A |
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13. |
Water is a mixture of |
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a. CO and H2 |
b. CO2 and H2O |
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d. CO, H2 and N2 |
: A |
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14. |
Phorone is obtained by the condensation of |
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a. 2 molecules of CH3-CHO |
b. 2 molecules of CH3-CO-CH3 |
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d. 3 molecules of
CH3-CO-CH3 |
: D |
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15. |
The value of Van der Waals constant 'a' is the largest for |
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a. O2 |
b. NH3 |
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d. N2 |
: B |
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16. |
Proton is |
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a. Alpha particle |
b. Ionized hydrogen atom |
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d. Ionized hydrogen molecule |
: B |
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17. |
In square close packing the central sphere is in contact with ----- spheres in one layer |
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a. 6 |
b. 12 |
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d. 4 |
: D |
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18. |
The pH of an aqueous solution of CH3COONa will be |
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a. 3 |
b. 7 |
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d. 14 |
: C |
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19. |
GUN cotton contains |
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a. glucose |
b. pyrolyxin |
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d. cellulose trinitrate |
: D |
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20. |
The total energy of the electron in hydrogen atom is |
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a. Less than zero |
b. Equal to zero |
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d. Greater than zero |
: A |
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21. |
For a reaction in equilibrium |
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a. there is no volume change |
b. the reaction has stopped completely |
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d. the forward reaction is faster than the reverse reaction |
: C |
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22. |
In the metallurgy of iron, limestone is added to blast furnace, the calcium on ends up in: |
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a. slag |
b. gange |
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d. calcium oxide |
: A |
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23. |
When conc. HNO3 is heated with P2O5,
it forms |
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a. N2O |
b. NO |
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d. N2O5 |
: D |
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24. |
The first ionization potential will be maximum for |
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a. lithium |
b. hydrogen |
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d. iron |
: B |
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25. |
LEUCO compound havig highest Pkb value among
the following is |
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a. (CH3)3N |
b. (CH3)2NH |
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d. NH3 |
: D |
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26. |
The rate of reaction is doubled for every 100
rise in temperature. The increase in reaction rate as a result of temperature
rise from 100 to 1000 is: |
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a. 112 |
b. 512 |
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d. 614 |
: B |
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27. |
The shape of XeF2 molecule is |
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a. tetrahedral |
b. pyramidal |
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d. linear |
: D |
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28. |
The number of ions formed when cupramonium sulphate dissolved in water is |
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a. one |
b. two |
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d. zero |
: B |
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29. |
TiCl4 is readily hydrolyzed into |
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a. TiO2 |
b. Ti2O3 |
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d. [Ti(OH2)] |
: A |
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30. |
The unit of specific conductivity is |
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a. ohms cm-1 |
b. ohms cm-2 |
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d. ohms-1 cm-1 |
: D |
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31. |
Heavy water is |
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a. water containing sulphates of Ca and Mg |
b. water containing heavy ions |
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d. D2O |
: D |
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32. |
The work done in
changing one mole of water at 1000C
to steam at 1000C and one atmospheric pressure is given by |
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a. 310 J |
b. 31 J |
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d. 3100 J |
: D |
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33. |
Potassium crystallizes in a body centered lattice. Hence the coordination number of potassium in potassium metal: |
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a. zero |
b. 8 |
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d. 4 |
: B |
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34. |
Electron transfer chain reactions are observed in |
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a. cellular respiration |
b. glycolysis |
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d. all the above |
: A |
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35. |
HVZ reaction is not given by |
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a. HCOOH |
b. C6H5COOH |
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d. all the above |
: D |
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36. |
Michalis Menten mechanism is related with |
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a. thermodynamics of irreversible systems |
b. fugacity |
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d. kinetic analysis of enzyme catalyzed reactions |
: D |
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37. |
The ionizing power of β-particle
is ......... times more than that of
α-particles |
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a. 10+2 |
b. 10-1 |
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d. 10-4 |
: C |
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38. |
Iron is rendered passive when treated with: |
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a. H2SO4 |
b. HCl |
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d. HNO3 |
: D |
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39. |
The appropriate current in amp/sec necessary to produce O2
gas at the rate of 10-3 litre per second is |
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a. 1.723 |
b. 0.1723 |
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d. 172.3 |
: C |
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40. |
White phosphorous contains |
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a. P2 molecules |
b. P6 molecules |
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d. P8 molecules |
: C |
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41. |
Out of the following the most acidic is |
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a. As2O3 |
b. P2O3 |
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d. Bi2O3 |
: B |
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42. |
Two electrons in an orbital are distinguished by |
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a. Spin quantum number |
b. Subsidiary quantum number |
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d. Principle quantum number |
: A |
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43. |
The number of gram atoms present in 22.4 g helium is |
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a. 2 |
b. 2.1 |
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d. 11.2 |
: C |
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44. |
Which of the following is a heterogeneous mixture? |
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a. Sand and Sugar |
b. Smoke |
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d. All the above |
: D |
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45. |
A chemical system is in equilibrium. Addition of a catalyst would result in |
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a. increase in the rate of forward reaction |
b. increase in the rate of reverse reaction |
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d. increase the amount of heat evolved in the reaction |
: C |
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46. |
The shape of NH3 molecule is |
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a. tetrahedral |
b. pyramidal |
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d. linear |
: B |
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47. |
Change in the internal energy of one mole of Argon during isothermal expansion is |
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a. 100 cals |
b. 140 cals |
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d. zero |
: D |
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48. |
Isotonic solutions have same |
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a. Vapour pressure |
b. Molality |
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d. Mole fraction |
: C |
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49. |
The hydrolysis of
methyl formate in acid solutions has
rate expression rate = k[HCOOCH3][H+], the balanced
equation being HCOOCH3 + H2O ¾¾¾¾®
HCOOH + CH3OH The rate law contains [H+] through the
balanced equation does not contain [H+] because: |
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a. more for convenience to express the rate law |
b. H+
ion is a catalyst |
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d. all acids contain H+ ions |
: B |
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50. |
Magnetic quantum number designates |
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a. Size of orbitals |
b. Spatial orientation of orbitals |
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d. Orbital angular momentum |
: B |