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Chemistry - Model Questions for Engineering Entrance Tests

 

 
1.

The number of moles of solute present in 1000 ml of the water and aqueous solution are respectively called
  a. Morarity & Morality
b. Morality & Molarity
 
d. Normality & Molality
: B
 
2.

Boltzmann constant with respect to gas constant is
  a. Gas constant for 100 molecules
b. Gas constant for 10 mole of gas
 
d. Gas constant for 1 molecule only
: D
 
3.

When Fe(OH)3 sol is added to As2S3 sol, then
  a. a new solution is formed
b. an emulsion is formed
 
d. flocculation takes place
: D
 
4.

The number of significant digits in 0.00002 and 20,000 respectively are
  a. 1 and 5
b. 1 and 1
 
d. 6 and 5
: A
 
5.

In fluorite structure, the arrangement of spheres is
  a. acc
b. hcc
 
d. ccp
: D
 
6.

1 mole of hydrated CuSO4 contains
  a. 90 moles of water
b. 90 atoms of water
 
d. 9 g of oxygen
: C
 
7.

During the extraction of Fe, slag obtained is
  a. FeO
b. FeSiO3
 
d. CaSiO3
: D
 
8.

Acetaminophen is a
  a. analgesics
b. disinfectant
 
d. none of these
: C
 
9.

Joule - Thomson effect is zero in the case of
  a. Real gas
b. Permanent gas
 
d. Non ideal gas
: C
 
10.

The enthalpies of elements in their standard states are taken as zero. Hence the enthalpy of formation of a compound
  a. should always be negative
b. should always be positive
 
d. may be positive or negative
: D
 
11.

To a mixture of acetic acid and sodium acetate a further amount of sodium acetate is added. The pH of the mixture:
  a. increases
b. decreases
 
d. not predictable
: A
 
12.

The product of atomic weight and specific heat for solid elements in k cal / mol is
  a. 6.4
b. 5
 
d. 5.6
: A
 
13.

Water is a mixture of
  a. CO and H2
b. CO2 and H2O
 
d. CO, H2 and N2
: A
 
14.

Phorone is obtained by the condensation of
  a. 2 molecules of CH3-CHO
b. 2 molecules of CH3-CO-CH3
 
d. 3 molecules of CH3-CO-CH3
: D
 
15.

The value of Van der Waals constant 'a' is the largest for
  a. O2
b. NH3
 
d. N2
: B
 
16.

Proton is
  a. Alpha particle
b. Ionized hydrogen atom
 
d. Ionized hydrogen molecule
: B
 
17.

In square close packing the central sphere is in contact with ----- spheres in one layer
  a. 6
b. 12
 
d. 4
: D
 
18.

The pH of an aqueous solution of CH3COONa will be
  a. 3
b. 7
 
d. 14
: C
 
19.

GUN cotton contains
  a. glucose
b. pyrolyxin
 
d. cellulose trinitrate
: D
 
20.

The total energy of the electron in hydrogen atom is
  a. Less than zero
b. Equal to zero
 
d. Greater than zero
: A
 
21.

For a reaction in equilibrium
  a. there is no volume change
b. the reaction has stopped completely
 
d. the forward reaction is faster than the reverse reaction
: C
 
22.

In the metallurgy of iron, limestone is added to blast furnace, the calcium on ends up in:
  a. slag
b. gange
 
d. calcium oxide
: A
 
23.

When conc. HNO3 is heated with P2O5, it forms
  a. N2O
b. NO
 
d. N2O5
: D
 
24.

The first ionization potential will be maximum for
  a. lithium
b. hydrogen
 
d. iron
: B
 
25.

LEUCO compound havig highest Pkb value among the following is
  a. (CH3)3N
b. (CH3)2NH
 
d. NH3
: D
 
26.

The rate of reaction is doubled for every 100 rise in temperature. The increase in reaction rate as a result of temperature rise from 100 to 1000 is:
  a. 112
b. 512
 
d. 614
: B
 
27.

The shape of XeF2 molecule is
  a. tetrahedral
b. pyramidal
 
d. linear
: D
 
28.

The number of ions formed when cupramonium sulphate dissolved in water is
  a. one
b. two
 
d. zero
: B
 
29.

TiCl4 is readily hydrolyzed into
  a. TiO2
b. Ti2O3
 
d. [Ti(OH2)]
: A
 
30.

The unit of specific conductivity is
  a. ohms cm-1
b. ohms cm-2
 
d. ohms-1 cm-1
: D
 
31.

Heavy water is
  a. water containing sulphates of Ca and Mg
b. water containing heavy ions
 
d. D2O
: D
 
32.

The work done in changing one mole of water at 1000C to steam at 1000C and one atmospheric pressure is given by
  a. 310 J
b. 31 J
 
d. 3100 J
: D
 
33.

Potassium crystallizes in a body centered lattice. Hence the coordination number of potassium in potassium metal:
  a. zero
b. 8
 
d. 4
: B
 
34.

Electron transfer chain reactions are observed in
  a. cellular respiration
b. glycolysis
 
d. all the above
: A
 
35.

HVZ reaction is not given by
  a. HCOOH
b. C6H5COOH
 
d. all the above
: D
 
36.

Michalis Menten mechanism is related with
  a. thermodynamics of irreversible systems
b. fugacity
 
d. kinetic analysis of enzyme catalyzed reactions
: D
 
37.

The ionizing power of β-particle is ......... times more than that of α-particles
  a. 10+2
b. 10-1
 
d. 10-4
: C
 
38.

Iron is rendered passive when treated with:
  a. H2SO4
b. HCl
 
d. HNO3
: D
 
39.

The appropriate current in amp/sec necessary to produce O2 gas at the rate of 10-3 litre per second is
  a. 1.723
b. 0.1723
 
d. 172.3
: C
 
40.

White phosphorous contains
  a. P2 molecules
b. P6 molecules
 
d. P8 molecules
: C
 
41.

Out of the following the most acidic is
  a. As2O3
b. P2O3
 
d. Bi2O3
: B
 
42.

Two electrons in an orbital are distinguished by
  a. Spin quantum number
b. Subsidiary quantum number
 
d. Principle quantum number
: A
 
43.

The number of gram atoms present in 22.4 g helium is
  a. 2
b. 2.1
 
d. 11.2
: C
 
44.

Which of the following is a heterogeneous mixture?
  a. Sand and Sugar
b. Smoke
 
d. All the above
: D
 
45.

A chemical system is in equilibrium. Addition of a catalyst would result in
  a. increase in the rate of forward reaction
b. increase in the rate of reverse reaction
 
d. increase the amount of heat evolved in the reaction
: C
 
46.

The shape of NH3 molecule is
  a. tetrahedral
b. pyramidal
 
d. linear
: B
 
47.

Change in the internal energy of one mole of Argon during isothermal expansion is
  a. 100 cals
b. 140 cals
 
d. zero
: D
 
48.

Isotonic solutions have same
  a. Vapour pressure
b. Molality
 
d. Mole fraction
: C
 
49.

The hydrolysis of methyl formate in acid solutions has rate expression rate = k[HCOOCH3][H+], the balanced equation being HCOOCH3 + H2O ¾¾¾¾® HCOOH + CH3OH The rate law contains [H+] through the balanced equation does not contain [H+] because:
  a. more for convenience to express the rate law
b. H+ ion is a catalyst
 
d. all acids contain H+ ions
: B
 
50.

Magnetic quantum number designates
  a. Size of orbitals
b. Spatial orientation of orbitals
 
d. Orbital angular momentum
: B
 
 
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